Yttrium(III) complex with 1,10-phenanthroline: Crystal structure and spectroscopic studies

被引：0

作者：

Moodi, A. ^{[1
]}

Khorasani-Motlagh, M. ^{[1
]}

Noroozifar, M. ^{[1
]}

Patrick, B. O. ^{[2
]}

机构：

[1] Univ Sistan & Baluchestan, Dept Chem, Zahedan, Iran

[2] Univ British Columbia, Dept Chem, Vancouver, BC, Canada

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 02期

关键词：

yttrium(III) complex; crystal structure; 1,10-phenanthroline; X-ray diffraction analysis; 2,2'-BIPYRIDINE; NITRATE;

D O I：

10.1134/S002247661402022X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

YCl3 center dot 6H(2)O reacts with 1,10-phenanthroline (phen) to yield a complex of 1:2 yttrium:ligand stoichiometry. The yttrium(III) complex is characterized by the elemental analysis, UV-Vis, IR as well as the X-ray diffraction analysis. The crystal of [Y(phen)(2)Cl(H2O)(3)]Cl-2 center dot H2O obtained from a methanol solution crystallizes in the triclinic system, space group P (1) over bar, Z = 2, a = 10.3236(4) angstrom, b = 10.4566(4) angstrom, c = 12.5270(5) angstrom, alpha = 97.354(2)degrees, beta = 108.740(2)degrees, gamma = 93.458(2)degrees, R-int = 0.046. The Y(III) ion is eight-coordinated by four nitrogen, three oxygen atoms and one chlorine atom.

引用

页码：337 / 341

页数：5

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