Yttrium(III) complex with 1,10-phenanthroline: Crystal structure and spectroscopic studies

被引：0
|
作者：
Moodi, A. [1 ]
Khorasani-Motlagh, M. [1 ]
Noroozifar, M. [1 ]
Patrick, B. O. [2 ]
机构：
[1] Univ Sistan & Baluchestan, Dept Chem, Zahedan, Iran
[2] Univ British Columbia, Dept Chem, Vancouver, BC, Canada
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 02期
关键词：
yttrium(III) complex; crystal structure; 1,10-phenanthroline; X-ray diffraction analysis; 2,2'-BIPYRIDINE; NITRATE;
D O I：
10.1134/S002247661402022X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
YCl3 center dot 6H(2)O reacts with 1,10-phenanthroline (phen) to yield a complex of 1:2 yttrium:ligand stoichiometry. The yttrium(III) complex is characterized by the elemental analysis, UV-Vis, IR as well as the X-ray diffraction analysis. The crystal of [Y(phen)(2)Cl(H2O)(3)]Cl-2 center dot H2O obtained from a methanol solution crystallizes in the triclinic system, space group P (1) over bar, Z = 2, a = 10.3236(4) angstrom, b = 10.4566(4) angstrom, c = 12.5270(5) angstrom, alpha = 97.354(2)degrees, beta = 108.740(2)degrees, gamma = 93.458(2)degrees, R-int = 0.046. The Y(III) ion is eight-coordinated by four nitrogen, three oxygen atoms and one chlorine atom.
引用
收藏
页码：337 / 341
页数：5
相关论文
共 50 条
  • [1] Yttrium(III) complex with 1,10-phenanthroline: Crystal structure and spectroscopic studies
    A. Moodi
    M. Khorasani-Motlagh
    M. Noroozifar
    B. O. Patrick
    [J]. Journal of Structural Chemistry, 2014, 55 : 337 - 341
  • [2] Crystal and molecular structure of trinitratobis(1,10-phenanthroline)neodymium(III)
    Antsyshkina, AS
    Sadikov, GG
    Rodnikova, MN
    Mikhailichenko, AI
    Nevzorova, LV
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (03) : 361 - 366
  • [3] Synthesis, Crystal Structure, and Thermal Properties of a Holmium(III) Benzoate Complex with 1,10-Phenanthroline
    Wang, Juan-Fen
    Ren, Ning
    Zhang, Jian-Jun
    Wu, Ke-Zhong
    Wang, Shu-Ping
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (11): : 4982 - 4989
  • [4] Crystal Structure and Properties of a Terbium Benzoate Complex with 1,10-Phenanthroline
    WANG Rui-Fena② WANG Shu-Pinga SHI Shi-Kaoa ZHANG Jian-Junb a(College of Chemistry
    [J]. Chinese Journal of Structural Chemistry, 2004, (11) : 1300 - 1304
  • [5] Molecular and Crystal Structure of 1,10-Phenanthroline Complex with Nitrosonium Cation
    R. V. Andreev
    G. I. Borodkin
    Yu. V. Gatilov
    V. G. Shubin
    [J]. Russian Journal of Organic Chemistry, 2002, 38 : 845 - 850
  • [6] Molecular and crystal structure of 1,10-phenanthroline complex with nitrosonium cation
    Andreev, RV
    Borodkin, GI
    Gatilov, YV
    Shubin, VG
    [J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (06) : 845 - 850
  • [7] Spectroscopic and theoretical studies on copper(II) complex of maleinitriledithiolate and 1,10-phenanthroline
    Yang, LF
    Peng, ZH
    Ren, XM
    Cheng, GZ
    Cai, P
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2001, 57 (14) : 2745 - 2754
  • [8] Synthesis and crystal structure of a new dysprosium(III) complex with 2-fluorobenzoato and 1,10-phenanthroline
    Li, Xia
    Zhang, Zhuo-Yong
    Song, Hai-Bin
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (02) : 99 - 103
  • [9] CRYSTAL-STRUCTURE OF TRIS(ACETYLACETONATO)(1,10-PHENANTHROLINE) EUROPIUM(III)
    WATSON, WH
    WILLIAMS, RJ
    STEMPLE, NR
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (02): : 501 - &
  • [10] Synthesis and crystal structure of a new dysprosium(III) complex with 2-fluorobenzoato and 1,10-phenanthroline
    Xia Li
    Zhuo-Yong Zhang
    Hai-Bin Song
    [J]. Journal of Chemical Crystallography, 2006, 36 : 99 - 103
12345