Graphene Oxide: An Efficient Acid Catalyst for Alcoholysis and Esterification Reactions

被引：92

作者：

Zhu, Shanhui ^{[1
]}

Chen, Chengmeng ^{[1
,2
]}

Xue, Yanfeng ^{[1
,3
]}

Wu, Jianbing ^{[1
,3
]}

Wang, Jianguo ^{[1
]}

Fan, Weibin ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China

[2] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

CHEMCATCHEM | 2014年 / 6卷 / 11期

基金：

中国国家自然科学基金;

关键词：

alcoholysis; biofuels; esterification; graphene oxide; heterogeneous catalysis; FURFURYL ALCOHOL; ETHYL LEVULINATE; SOLID ACID; GRAPHITE OXIDE; CONVERSION; CELLULOSE; HETEROPOLYACIDS; CARBOCATALYST; HYDROLYSIS; GLYCEROL;

D O I：

10.1002/cctc.201402574

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Evidence is presented for graphene oxide (GO), prepared by modified Hummers method, as a highly active, selective and reusable solid-acid catalyst for the production of alkyl levulinates via alcoholysis or esterification. 95.5% yield of ethyl levulinate was achieved by GO in furfuryl alcohol alcoholysis. Moreover, the surface SO3H groups were identified as the primary active sites, while the surface carboxyl groups worked synergistically to adsorb furfuryl alcohol.

引用

页码：3080 / 3083

页数：4

共 50 条

[1] Fractional distribution of graphene oxide and its potential as an efficient and reusable solid catalyst for esterification reactions
Mungse, Harshal P.
Bhakuni, Niharika
Tripathi, Deependra
Sharma, Om P.
Sain, Bir
Khatri, Om P.
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2014, 27 (12) : 944 - 951
[2] Supported cobalt oxide nanoparticles as efficient catalyst in esterification and amidation reactions
Rajabi, Fatemeh
Raessi, Mojdeh
Arancon, Rick Ad.
Saidi, Mohammad Reza
Luque, Rafael
CATALYSIS COMMUNICATIONS, 2015, 59 : 122 - 126
[3] Sulfonated Reduced Graphene Oxide: An Acid Catalyst that Efficiently Promotes the Esterification of Glycerol
Luisa Damaris Ramos Riascos
Alfonso Enrique Ramírez Sanabria
Gerardo Andrés Torres Rodríguez
Alexander Sachse
Cristian David Miranda Muñoz
Topics in Catalysis, 2022, 65 : 957 - 965
[4] Sulfonated Reduced Graphene Oxide: An Acid Catalyst that Efficiently Promotes the Esterification of Glycerol
Ramos Riascos, Luisa Damaris
Ramirez Sanabria, Alfonso Enrique
Torres Rodriguez, Gerardo Andres
Sachse, Alexander
Miranda Munoz, Cristian David
TOPICS IN CATALYSIS, 2022, 65 (7-8) : 957 - 965
[5] Chemical modification of reduced graphene oxide with sulfonic acid groups: Efficient solid acids for acetalization and esterification reactions
Hosseini, Mandiyeh-Sadat
Masteri-Farahani, Majid
Shahsavarifar, Samaneh
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 102 : 34 - 43
[6] Graphene oxide as a facile solid acid catalyst for the production of bioadditives from glycerol esterification
Gao, Xiaoqing
Zhu, Shanhui
Li, Yongwang
CATALYSIS COMMUNICATIONS, 2015, 62 : 48 - 51
[7] Sulfamic acid: An efficient acid catalyst for esterification of FFA
Montes D'Oca, Marcelo G.
Soares, Rafael Marinho
de Moura, Renata Rodrigues
Granjao, Vinicius de Freitas
FUEL, 2012, 97 : 884 - 886
[8] Sulfonated charcoal as a mild and efficient catalyst for esterification and trans-esterification reactions
Iranpoor, N.
Firouzabadi, H.
Farahi, S.
Journal of Sulfur Chemistry, 2007, 28 (06) : 581 - 587
[9] Sulfonated Graphene Oxide as an Efficient Solid Acid Carbocatalyst for Esterification of Fatty Acids with Polyols
Khatri, Praveen K.
Kumar, Prashant
Nagendramma, Ponnnekanti
Jain, Suman L.
LETTERS IN ORGANIC CHEMISTRY, 2018, 15 (06) : 508 - 514
[10] Green Synthesis of Iron Oxide-Based Superacid Catalysts Modified with Graphene Oxide for Efficient Esterification Reactions
Abeer A. Elssawy
Mohsen M. T. El-Tahawy
Hussein A. Khalaf
Catalysis Surveys from Asia, 2025, 29 (2) : 111 - 126

← 1 2 3 4 5 →