State of the catalyst during carbon nanotube growth

被引：82
|
作者：
Wirth, C. T. [1 ]
Hofmann, S. [1 ]
Robertson, J. [1 ]
机构：
[1] Univ Cambridge, Dept Engn, Cambridge CB2 1PZ, England
来源：
DIAMOND AND RELATED MATERIALS | 2009年 / 18卷 / 5-8期
关键词：
carbon nanotubes; growth mechanism; chemical vapour deposition; catalyst; CHEMICAL-VAPOR-DEPOSITION; GAS-PHASE SYNTHESIS; NANOPARTICLE CATALYSTS; METAL NANOPARTICLES; SUPPORTED CATALYSTS; GOLD; MECHANISM; TEMPERATURE; NUCLEATION; SPECTROSCOPY;
D O I：
10.1016/j.diamond.2009.01.030
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
We review our in-situ X-ray photoemission (XPS) and in-situ transmission electron microscopy studies which determined that the catalyst is in the metallic state for Fe. Co and Ni catalysts. We show that the existence of surface carbide phases in related catalytic reactions could account for the observation of carbide peaks in XPS. The observed catalytic activity of gold is discussed in terms of carbon solubility. reaction rates, and surface coordination numbers. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：940 / 945
页数：6
相关论文
共 50 条
  • [21] Effect of catalyst preparation on the yield of carbon nanotube growth
    Escobar, Mariano
    Rubiolo, Gerardo
    Candal, Roberto
    Goyanes, Silvia
    PHYSICA B-CONDENSED MATTER, 2009, 404 (18) : 2795 - 2798
  • [22] A jellium model of a catalyst particle in carbon nanotube growth
    Artyukhov, Vasilii I.
    Liu, Mingjie
    Penev, Evgeni S.
    Yakobson, Boris I.
    JOURNAL OF CHEMICAL PHYSICS, 2017, 146 (24):
  • [23] Abrasion as a Catalyst Deposition Technique for Carbon Nanotube Growth
    Alvarez, Noe T.
    Pint, Cary L.
    Hauge, Robert H.
    Tour, James M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (41) : 15041 - 15048
  • [24] Thermodynamics of the formation of catalyst clusters for carbon nanotube growth
    S. V. Bulyarskii
    O. V. Pyatilova
    A. V. Tsygantsov
    A. S. Basaev
    V. A. Galperin
    A. A. Pavlov
    Yu. P. Shaman
    Semiconductors, 2010, 44 : 1718 - 1722
  • [25] Thermodynamics of the Formation of Catalyst Clusters for Carbon Nanotube Growth
    Bulyarskii, S. V.
    Pyatilova, O. V.
    Tsygantsov, A. V.
    Basaev, A. S.
    Galperin, V. A.
    Pavlov, A. A.
    Shaman, Yu. P.
    SEMICONDUCTORS, 2010, 44 (13) : 1718 - 1722
  • [26] Effect of catalyst preparation on the carbon nanotube growth rate
    Yu, ZX
    Chen, D
    Totdal, B
    Holmen, A
    CATALYSIS TODAY, 2005, 100 (3-4) : 261 - 267
  • [27] Direct observation of morphological evolution of a catalyst during carbon nanotube forest growth: new insights into growth and growth termination
    Jeong, Seojeong
    Lee, Jaegeun
    Kim, Hwan-Chul
    Hwang, Jun Yeon
    Ku, Bon-Cheol
    Zakharov, Dmitri N.
    Maruyama, Benji
    Stach, Eric A.
    Kim, Seung Min
    NANOSCALE, 2016, 8 (04) : 2055 - 2062
  • [28] Support-Catalyst-Gas Interactions during Carbon Nanotube Growth on Metallic Ta Films
    Bayer, B. C.
    Hofmann, S.
    Castellarin-Cudia, C.
    Blume, R.
    Baehtz, C.
    Esconjauregui, S.
    Wirth, C. T.
    Oliver, R. A.
    Ducati, C.
    Knop-Gericke, A.
    Schloegl, R.
    Goldoni, A.
    Cepek, C.
    Robertson, J.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (11): : 4359 - 4369
  • [29] Catalyst design for carbon nanotube growth using atomistic modeling
    Pint, Cary L.
    Bozzolo, Guillermo
    Hauge, Robert
    NANOTECHNOLOGY, 2008, 19 (40)
  • [30] Effect of Morphology of Catalyst Thin Film on Carbon Nanotube Growth
    Li, Gang
    INORGANIC MATERIALS, 2010, 46 (10) : 1072 - 1076
12345