Reduction of carbonyl compounds with NaBH4 under ultrasound irradiation and aprotic condition

被引:11
|
作者
Zeynizadeh, B [1 ]
Yahyaei, S [1 ]
机构
[1] Urmia Univ, Fac Sci, Dept Chem, Urmia 57159165, Iran
关键词
reduction; sodium borohydride; ultrasound; carbonyl compounds;
D O I
10.1515/znb-2004-0612
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A variety of carbonyl compounds are reduced,to their corresponding alcohols with sodium borohydride under ultrasound irradiation and aprotic condition. Reduction reactions are performed in THF at room temperature or under reflux condition. The product alcohols were obtained in good to excellent yields. The chemoselective reduction of aldehydes over ketones was achieved successfully with this system.
引用
收藏
页码:704 / 710
页数:7
相关论文
共 50 条
  • [31] SELECTIVE REDUCTION OF OLEFINS BY NABH4 AND CO(11)
    CHUNG, SK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 450 - 450
  • [32] Theoretical Study of Resorufin Reduction Mechanism by NaBH4
    Song, Ping
    Ruan, Mingbo
    Sun, Xiujuan
    Zhang, Yuwei
    Xu, Weilin
    JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (34): : 10224 - 10231
  • [33] Biomimetic reduction of nimesulide with NaBH4 catalyzed by metalloporphyrins
    Chauhan, SMS
    Kandadai, SA
    Kumar, A
    CHEMICAL & PHARMACEUTICAL BULLETIN, 2002, 50 (10) : 1421 - 1422
  • [34] Suitability of cyclic voltammetry for the measurement of sodium borohydride (NaBH4) in a solution of Cr(VI)/organic compounds/NaBH4
    Njoya, Ousmanou
    Pam, Seidou
    Oyono, Joseph Sadrack Ondoua
    WATER PRACTICE AND TECHNOLOGY, 2024, 19 (07) : 2920 - 2928
  • [35] DETERMINATION OF THE STRUCTURE OF PRODUCTS OF THE REDUCTION OF PYRIDOSTIGMINE WITH NABH4
    HORSTMANN, V
    HAFELINGER, G
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1985, 40 (10): : 1401 - 1408
  • [36] Theoretical Study on the Mechanism and Diastereoselectivity of NaBH4 Reduction
    Suzuki, Yasumitsu
    Kaneno, Daisuke
    Tomoda, Shuji
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (11): : 2578 - 2583
  • [37] Mechanistic rationale for the NaBH4 reduction of α-keto esters
    Dalla, V
    Catteau, JP
    Pale, P
    TETRAHEDRON LETTERS, 1999, 40 (28) : 5193 - 5196
  • [38] Asymmetric Induction by β-Cyclodextrins in NaBH4 Reduction of Ketones
    Kwanghee Koh Park
    Woo-Jeon Sim
    Joon Woo Park
    Journal of inclusion phenomena and molecular recognition in chemistry, 1997, 27 : 41 - 48
  • [39] ASYMMETRIC REDUCTION OF KETONES WITH NABH4 IN PRESENCE OF LECITHIN
    DOIUCHI, T
    MINOURA, Y
    ISRAEL JOURNAL OF CHEMISTRY, 1977, 15 (1-2) : 84 - 88
  • [40] NABH4 REDUCTION OF KETONES IN THE SOLID-STATE
    TODA, F
    KIYOSHIGE, K
    YAGI, M
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (03) : 320 - 321