Transition-Metal-Catalyzed Site-Selective Cross-Coupling of Di- and Polyhalogenated Compounds

被引：100
|
作者：
Wang, Jia-Rui [1 ]
Manabe, Kei [1 ]
机构：
[1] RIKEN, Adv Sci Inst, Manabe Initiat Res Unit, Wako, Saitama 3510198, Japan
来源：
SYNTHESIS-STUTTGART | 2009年 / 09期
关键词：
cross-coupling; catalysis; halides; transition metals; site selectivity; TRISUBSTITUTED CONJUGATED DIENES; HIGHLY STEREOSELECTIVE-SYNTHESIS; DIELS-ALDER REACTION; ONE-POT SYNTHESIS; C-F ACTIVATION; GRIGNARD-REAGENTS; ARYL FLUORIDES; SUZUKI REACTION; STEREOCONTROLLED SYNTHESIS; REGIOSELECTIVE SYNTHESIS;
D O I：
10.1055/s-0029-1216632
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review highlights transition-metal-catalyzed cross-coupling reactions in which one of the halogen atoms (or pseudohalogen groups) of di- or polyhalogenated compounds is converted site-selectively into another group. The compounds are categorized as halogenated alkenes, heteroarene derivatives, benzene derivatives, and alkanes. Enantioselective cross-coupling of substrates having two enantiotopic halo groups is also described.
引用
收藏
页码：1405 / 1427
页数：23
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