ON THE PHOTOISOMERIZATION OF THIOPHENE AND THIAZOLE DERIVATIVES

被引：6

作者：

D'Auria, Maurizio ^{[1
]}

Racioppi, Rocco ^{[1
]}

机构：

[1] Univ Basilicata, Dept Chem, I-85100 Potenza, Italy

来源：

HETEROCYCLES | 2009年 / 78卷 / 03期

关键词：

PHOTOCHEMICAL ISOMERIZATION; AB-INITIO; ARYLTHIOPHENE REARRANGEMENTS; PHOTOTRANSPOSITION CHEMISTRY; HETEROCYCLIC SERIES; PHOTO-ISOMERIZATION; DEWAR THIOPHENE; FURAN; PHOTOREARRANGEMENTS; PHENYLTHIAZOLES;

D O I：

10.3987/COM-08-11571

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photochemical isomerization of thienyl and thiazolyl derivatives can be explained by assuming the formation of the Dewar isomer. The isomerization of the Dewar isomer towards the most stable one can account for the observed reaction. No biradical intermediate was found. In the case of thiophene an isomerization of the Dewar thiophene allows the formation of a tricyclic intermediate; a retroelectrocyclic reaction can afford the reaction product. This tricyclic intermediate cannot be formed in the photoisomerization of thiazole derivative.

引用

页码：737 / 748

页数：12

共 50 条

[31] Synthesis, antitumor and antioxidant evaluation of some new thiazole and thiophene derivatives incorporated coumarin moiety
Gouda, Moustafa A.
Berghot, Moged A.
Baz, Eman A.
Hamama, Wafaa S.
MEDICINAL CHEMISTRY RESEARCH, 2012, 21 (07) : 1062 - 1070
[32] Synthesis of Novel Thiophene, Thiazole and Coumarin Derivatives Based on Benzimidazole Nucleus and Their Cytotoxicity and Toxicity Evaluations
Mohareb, Rafat Milad
Abdallah, Amira Elsayed Mahmoud
Mohamed, Abeer Abdelazeem
CHEMICAL & PHARMACEUTICAL BULLETIN, 2018, 66 (03) : 309 - 318
[33] Novel Synthesis of Hydrazide-Hydrazone Derivatives and Their Utilization in the Synthesis of Coumarin, Pyridine, Thiazole and Thiophene Derivatives with Antitumor Activity
Mohareb, Rafat M.
Fleita, Daisy H.
Sakka, Ola K.
MOLECULES, 2011, 16 (01): : 16 - 27
[34] Uses of 2-(Thiophene-2-carbonylcarbamothioylthio)acetic Acid as a Good Synthon for Construction of Some New Thiazole and Annulated Thiazole Derivatives
Abd El-Mawgoud, Heba Kamal
Atta-Allah, Saad Ramadan
Hemdan, Magdy Mohamed
CHEMICAL & PHARMACEUTICAL BULLETIN, 2018, 66 (10) : 992 - 998
[35] SYNTHESIS OF MACROCYCLES, CONTAINING THIOPHENE AND THIAZOLE RINGS
GOLDFARB, YL
KRASNYANSKAYA, EA
DUDINOV, AA
TAITS, SZ
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1986, (06): : 841 - 844
[36] SYNTHESIS, CHARACTERIZATION AND ANTIOXIDANT PROPERTY OF NOVEL SERIES OF THIAZOLE BASED CHALCONES CARRYING THIOPHENE/FURAN DERIVATIVES
Nkurunziza, Jean Baptiste
Kalluraya, Balakrishna
INDIAN JOURNAL OF HETEROCYCLIC CHEMISTRY, 2016, 26 (1-2) : 69 - 74
[37] Synthesis of some new 2-substituted-4-sulfamoylphenylazo-thiophene and/or thiazole derivatives as antibacterial agents
Fadda, Ahmed A.
El-badraw, Afnan M.
Refat, Hala M.
Abdel-Latif, Ehab
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2016, 191 (05) : 778 - 785
[38] Synthesis and Characterization of Thiophene and Thiazole Containing Polymers
Ustamehmetoglu, B.
ELECTROCHIMICA ACTA, 2014, 122 : 130 - 140
[39] Novel synthesis of thiazole, coumarin, pyridine, thiophene and, thieno[2,3-b]pyridine derivatives
El-Taweel, FMA
Elagamey, AA
El-Kenawy, AA
Waly, MA
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 176 : 215 - 225
[40] THIAZOLE DERIVATIVES OF AMINOPROPANES
EKSTRAND, T
ACTA CHEMICA SCANDINAVICA, 1948, 2 (09): : 727 - 732

← 1 2 3 4 5 →