Kinetic study of addition of some carboxylic acids to 1,2-epoxy-3-phenoxypropane

被引：24

作者：

Bukowska, A ^{[1
]}

Bukowski, W ^{[1
]}

机构：

[1] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 1999年 / 3卷 / 06期

关键词：

D O I：

10.1021/op9900479

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The kinetics of addition of acetic, acrylic, or methacrylic acids to 1,2-epoxy-3-phenoxypropane (glycidyl phenyl ether) carried out in the presence of chromium(III) ethanoate have been studied. A kinetic model of the reaction has been proposed. The rake constants as web as the activation parameters have been evaluated. The reactivity of the acids in reactions with GPE and 1-chloro-2,3-epoxypropane (epichlorohydrin) without any solvent are compared. The compositions of reaction mixtures have been carefully determined.

引用

页码：432 / 436

页数：5

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