Kinetic study of addition of some carboxylic acids to 1,2-epoxy-3-phenoxypropane

被引：24
|
作者：
Bukowska, A [1 ]
Bukowski, W [1 ]
机构：
[1] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland
来源：
ORGANIC PROCESS RESEARCH & DEVELOPMENT | 1999年 / 3卷 / 06期
关键词：
D O I：
10.1021/op9900479
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The kinetics of addition of acetic, acrylic, or methacrylic acids to 1,2-epoxy-3-phenoxypropane (glycidyl phenyl ether) carried out in the presence of chromium(III) ethanoate have been studied. A kinetic model of the reaction has been proposed. The rake constants as web as the activation parameters have been evaluated. The reactivity of the acids in reactions with GPE and 1-chloro-2,3-epoxypropane (epichlorohydrin) without any solvent are compared. The compositions of reaction mixtures have been carefully determined.
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页码：432 / 436
页数：5
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