Anion-directed assembly of metal-organic coordination complexes from 1,3-imidazolidine-2-thione ligand and silver salts

被引：9
|
作者：
Zhu, Qinlei [1 ]
Huang, Rudan [1 ]
Lu, Kai [1 ]
Dong, Lanjun [1 ]
Hu, Changwen [1 ]
机构：
[1] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 14期
基金：
中国国家自然科学基金;
关键词：
Anion; Synthesize; 1,3-Imidazolidine-2-thione; Crystal structure; CRYSTAL-STRUCTURE; HETEROCYCLIC THIOAMIDES; RECEPTOR CHEMISTRY; HALIDE-COMPLEXES; COPPER(I); POLYMERS; HIGHLIGHTS; NETWORK; PYRIDINE-2-THIONE; NITROGEN;
D O I：
10.1016/j.ica.2009.07.030
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Five novel silver (I) complexes with 1,3-imidazolidine-2-thione ligand formulated as [Ag-2(eta(1)-SC3H6N2) (6)]SO4 (1), [Ag-2(mu(2)-SC3H6N2)(2)(eta(1)-SC3H6N2)(4)](NO3)(2) (2), [Ag(mu(2)-SC3H6N2)Br](n) (3), [Ag-2(mu(2)-SC3H6N2) (3)(CH3COO)(2)](n) (4), [Ag(mu(2)-SC3H6N2)Cl](n) (5) have been synthesized under similar conditions except for different anions and solvents. They are structurally characterized by elemental analysis, IR, TG and single crystal X- ray diffraction. Complex 1 is a binuclear complex, with SO42- anions as the counteranions. Complex 2 is a molecular binuclear silver cluster, with NO3 anions as the counteranions. Complex 3 shows a novel 2D lamella structure constructed by the S atom of 1,3-imidazolidine-2-thione ligand and Br- anions, and exhibits 12-membered metallacyclic rings in its structure. Complex 4 is a novel 2D layered polymer with a graphite-like array of silver (I) ions, with CH3COO- anion coordinated to silver(I) ions by O atom. Complex 5 shows a 3D diamond-like network structure constructed by the sulfur atom of 1,3-imidazolidine-2-thione ligand and Cl- anions. (c) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：4943 / 4952
页数：10
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