A novel open-framework cerium sulfate hydrate: Synthesis and characterization

被引：12
|
作者：
Yu, RB
Wang, D [1 ]
Chen, YF
Xing, XR
Ishiwata, S
Saito, T
Takano, M
机构：
[1] Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China
[2] Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China
[3] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
来源：
CHEMISTRY LETTERS | 2004年 / 33卷 / 09期
关键词：
D O I：
10.1246/cl.2004.1186
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel open-framework cerium sulfate hydrate [Ce-III(SO4)(1.5)(HSO4)(0.5)].0.5H(3)O has been synthesized hydrothermally, and characterized by single-crystal XRD, SEM, SQUID, and elemental analysis. In its structure, the CeO7 polyhedra and SO4 tetrahedra are connected via corner sharing in a strictly alternate manner to form an open-framework structure with a one-dimensional eight-membered ring channel system along the b axis. Protonated H2O molecules are accommodated in the channels.
引用
收藏
页码：1186 / 1187
页数：2
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