Synthesis of lignin model compound containing a β-O-4 linkage

被引：6

作者：

Mukhtar, Asma ^{[3
]}

Zaheer, Muhammad ^{[3
]}

Saeed, Muhammad ^{[1
]}

Voelter, Wolfgang ^{[2
]}

机构：

[1] Lahore Univ Management Sci, Dept Chem, SBA Sch Sci & Engn, Lahore 54792, Pakistan

[2] Eberhard Karls Univ Tubingen, Interfak Inst Biochem, Hoppe Seyler Str 4, D-72076 Tubingen, Germany

[3] Lahore Univ Management Sci, Dept Chem, SBA Sch Sci & Engn, Lahore 54792, Pakistan

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2017年 / 72卷 / 02期

关键词：

aromatic raw material; bio-waste; lignin; model compounds; beta-O-4; linkage; CATALYTIC CONVERSION; ARYL ETHERS; CHEMICALS; BIOMASS; CELLULOSE; FUELS; HYDROGENOLYSIS; TRANSFORMATION; HYDROLYSIS; MECHANISM;

D O I：

10.1515/znb-2016-0201

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Development of catalysts for efficient conversion of lignin polymer to value- added materials requires appropriately- functionalized lignin model compounds. The predominant structural feature of lignin biopolymer is an extensive network of beta-O-4 linkages. Access to large amounts of a model compound containing the beta-O-4 linkage is crucial for the valorisation of lignin biopolymer to aromatic raw materials. Starting from commercially available vanillin, synthesis of dilignol model compound, containing a beta-O-4 linkage, is accomplished in good overall yield.

引用

页码：119 / 124

页数：6

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