Li-ion storage and gas adsorption properties of porous polyimides (PIs)

被引：88
|
作者：
Tian, Dan [1 ,2 ]
Zhang, Hong-Zhou [3 ]
Zhang, Da-Shuai [1 ,2 ]
Chang, Ze [1 ,2 ]
Han, Jie [1 ,2 ]
Gao, Xue-Ping [3 ]
Bu, Xian-He [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[2] Nankai Univ, Tianjin Key Lab Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
[3] Nankai Univ, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China
来源：
RSC ADVANCES | 2014年 / 4卷 / 15期
关键词：
RECHARGEABLE LITHIUM BATTERIES; POSITIVE-ELECTRODE MATERIAL; HIGH-SURFACE-AREA; ORGANIC FRAMEWORKS; HIGH-POWER; SELECTIVE UPTAKE; CO2; CAPTURE; POLYMERS; PERFORMANCE; CONSTRUCTION;
D O I：
10.1039/c3ra45563g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this work, three polyimides (PIs) are successfully synthesized by the condensation reaction of an aromatic triamine with three difunctional aromatic dianhydrides. These materials show electrochemical lithium ion storage properties as cathodes for lithium-ion batteries. The aromatic dianhydride monomers are found to have significant effects on their performances. In addition, the polymer PI-1 shows narrow micropore size distributions and selective adsorption of CO2 over CH4 and N-2. Furthermore, PI-1 exhibits a high Q(st) value (11.7 kJ mol(-1)) for H-2 adsorption.
引用
收藏
页码：7506 / 7510
页数：5
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