Nitroxo spin-labelled calix[4]arene podands and cryptands: Allosteric regulation of spin-spin exchange interaction

被引：47
|
作者：
Ulrich, G
Turek, P
Ziessel, R
机构：
[1] ECOLE CHIM POLYMERES MAT,F-67008 STRASBOURG,FRANCE
[2] UNIV LOUIS PASTEUR STRASBOURG 1,INST CHARLES SADRON,F-67083 STRASBOURG,FRANCE
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 48期
关键词：
paramagnetic sensors; nitroxyl radicals; calix[4]arene; calixspin; calixbipy; EPR detection;
D O I：
10.1016/S0040-4039(96)02042-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hybrid calix[4]arene podands and ctyptands, each bearing two or four stable nitronyl-nitroxide radicals and two bipyridine subunits, exhibit through-space exchange interaction, the magnitude of which can be modulated by coordination of ZM(2+) cations at the bipyridine sites. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：8755 / 8758
页数：4
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