Simple field theoretical approach of Coulomb systems. Entropic effects

被引：2
|
作者：
di Caprio, D. [1 ]
Badiali, J. P. [1 ]
Holovko, M. [2 ]
机构：
[1] Univ Paris 06, CNRS, ENSCP, Lab Electrochem & Analyt Chem, F-75252 Paris 05, France
[2] Natl Acad Sci, Inst Condensed Matter Phys, UA-79011 Lvov, Ukraine
来源：
JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL | 2009年 / 42卷 / 21期
关键词：
ANOMALOUS TEMPERATURE-DEPENDENCE; DOUBLE-LAYER; MONTE-CARLO; CAPACITANCE; INTERFACE;
D O I：
10.1088/1751-8113/42/21/214038
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
We discuss a new simple field theory approach of Coulomb systems. Using a description in terms of fields, we introduce in a new way the statistical degrees of freedom in relation to the quantum mechanics. We show by a series of examples that these fundamental entropic effects can help account for physical phenomena in relation to Coulomb systems whether symmetric or asymmetric in valence. Overall, this gives a new understanding of these systems.
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页数：5
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