Simple field theoretical approach of Coulomb systems. Entropic effects

被引：2

作者：

di Caprio, D. ^{[1
]}

Badiali, J. P. ^{[1
]}

Holovko, M. ^{[2
]}

机构：

[1] Univ Paris 06, CNRS, ENSCP, Lab Electrochem & Analyt Chem, F-75252 Paris 05, France

[2] Natl Acad Sci, Inst Condensed Matter Phys, UA-79011 Lvov, Ukraine

来源：

JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL | 2009年 / 42卷 / 21期

关键词：

ANOMALOUS TEMPERATURE-DEPENDENCE; DOUBLE-LAYER; MONTE-CARLO; CAPACITANCE; INTERFACE;

D O I：

10.1088/1751-8113/42/21/214038

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We discuss a new simple field theory approach of Coulomb systems. Using a description in terms of fields, we introduce in a new way the statistical degrees of freedom in relation to the quantum mechanics. We show by a series of examples that these fundamental entropic effects can help account for physical phenomena in relation to Coulomb systems whether symmetric or asymmetric in valence. Overall, this gives a new understanding of these systems.

引用

页数：5

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