{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)

被引：0
|
作者：
Rehbein, Julia [1 ]
Schuermann, Markus [1 ]
Preut, Hans [1 ]
Hiersemann, Martin [1 ]
机构：
[1] Tech Univ Dortmund, Fak Chem, D-44221 Dortmund, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
ENANTIOSELECTIVE CLAISEN REARRANGEMENT; ALLYL VINYL ETHER;
D O I：
10.1107/S1600536809020364
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(C(17)H(30)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the asymmetric Gosteli-Claisen rearrangement, the Cu atom adopts a distorted cis-CuN(2)O(2) square-planar geometry arising from N,N'-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C-H center dot center dot center dot O contacts occur within the ligand and two weak intermolecular C-H center dot center dot center dot F bonds may help to establish the packing.
引用
收藏
页码：M737 / U499
页数：12
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