New molecular rearrangement of tricyclic spirofuranoid into the alpha,alpha-disubstituted p-semiquinoid system

被引：0

作者：

Sergeev, SV ^{[1
]}

Nikanorov, VA ^{[1
]}

Kharitonov, VG ^{[1
]}

Yanovsky, AI ^{[1
]}

Struchkov, YT ^{[1
]}

Rozenberg, VI ^{[1
]}

Reutov, OA ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 06期

关键词：

cyclohexadienones; alkylidenecyclohexadienes; spirofuranoids; molecular rearrangements;

D O I：

10.1007/BF01434245

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new acid-catalyzed molecular rearrangement of Z-2,3,4,5,6,7-hexahydro-3-methoxy-carbonyl-4 '-trichloromethyl-4',6,6-trimethylspiro[benzofuran-2,1'-[2,5]cyclohexadien]-4-one into 4-methyl-4-trichloromethyl-1-(4,4-dimethyl-2-hydroxy-6-oxocyclo-1-hexenyl)(methoxycarbonyl)methylene]-2,5-cyclohexadiene was found. The structure of the latter compound was confirmed analytically, by spectral data, and by X-ray diffraction study.

引用

页码：1499 / 1501

页数：3

共 20 条

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