Synthesis of mono- and bi-metallic dithiocarboxylate-alkyne complexes from sunlight driven insertion reaction and their antibacterial activity

被引：13

作者：

Patel, Sumanta K. ^{[1
]}

Tirkey, Vijaylakshmi ^{[1
]}

Mishra, Sasmita ^{[1
]}

Dash, Hirak R. ^{[2
]}

Das, Surajit ^{[2
]}

Shukla, Madhulata ^{[3
]}

Saha, Satyen ^{[3
]}

Mobin, Shaikh M. ^{[4
]}

Chatterjee, Saurav ^{[1
]}

机构：

[1] Natl Inst Technol, Dept Chem, Rourkela 769008, Orissa, India

[2] Natl Inst Technol, Dept Life Sci, Rourkela 769008, Orissa, India

[3] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India

[4] Indian Inst Technol, Sch Basic Sci, Indore 452017, Madhya Pradesh, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 749卷

关键词：

Bio-organometallic; Sunlight; Antibacterial; Dithiocarboxylate; RAY CRYSTAL-STRUCTURE; BIOORGANOMETALLIC CHEMISTRY; CYCLOPENTADIENYL-RUTHENIUM; ORGANOMETALLIC COMPLEXES; CARBONYL-COMPLEXES; CS2; DISULFIDE; LIGAND; ZINC; BOND;

D O I：

10.1016/j.jorganchem.2013.09.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sunlight driven synthesis, characterization and antibacterial evaluation of cyclopentadienyl based metal-dithiocarboxylate alkyne complexes, [LM(CO)(n)(eta(2)-S2C)C CR], [{L = eta(5)-C5H5, M = W, R = (eta(5)-C5H4) Fe(eta(5)-C5H5), n = 2}; {L = eta(5)-C5H5, M = W, R = -C(CH3)-CH2, n = 2}; {L = eta(5)-C5H5, M = Mo, R = -C(CH3)=CH2, n = 2}; {L = eta(5)-C5Me5, M = Fe, R = Ph, n = 1}] (5-8) have been carried out. Reactivity of metal-dithiocarboxylate alkyne complexes towards dicobaltoctacarbonyl were studied to obtain a tri-metallic dithiocarboxylate complex (9-11). Structural characterizations of 7 and 8 have been carried out crystallographically and DFT calculation was performed on compound 8 to understand the electronic properties of the complex. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：75 / 82

页数：8

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