Ruthenium-catalyzed cycloaddition of propargylic alcohols with phenol derivatives via allenylidene intermediates:: Catalytic use of the allenylidene ligand as the C3 unit

被引：138
|
作者：
Nishibayashi, Y
Inada, Y
Hidai, M
Uemura, S
机构：
[1] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
[2] Tokyo Univ Sci, Dept Mat Sci & Technol, Noda, Chiba 2788510, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 27期
关键词：
D O I：
10.1021/ja026168x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel ruthenium-catalyzed cycloaddition of propargylic alcohols with 2-naphthols and phenols bearing electron-donating groups via allenylidene intermediates has been developed to give the corresponding 1H-naphtho[2,1-b]pyrans and 4H-1-benzopyrans, respectively, in moderate to excellent yields with complete regioselectivity. Copyright © 2002 American Chemical Society.
引用
收藏
页码：7900 / 7901
页数：2
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