Diode laser study of the product branching ratio of the NH2(X B-2(1))+NO2 reaction

被引：26
|
作者：
Quandt, RW [1 ]
Hershberger, JF [1 ]
机构：
[1] N DAKOTA STATE UNIV,DEPT CHEM,CTR MAIN GRP CHEM,FARGO,ND 58105
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 22期
关键词：
D O I：
10.1021/jp960432p
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction of NH2(X B-2(1)) with NO2 was studied at room temperature using time-resolved infrared diode laser spectroscopy to detect N2O, H2O, and NO products, The N2O + H2O product channel was found to have a branching ratio of 0.14 +/- 0.02. Large amounts of NO were detected, bur secondary sources of this species prevent a quantitative determination of the branching ratio into the H2NO + NO channel. These results are in contrast to previously published branching ratio data.
引用
收藏
页码：9407 / 9411
页数：5
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