Diode laser study of the product branching ratio of the NH2(X B-2(1))+NO2 reaction

被引：26

作者：

Quandt, RW ^{[1
]}

Hershberger, JF ^{[1
]}

机构：

[1] N DAKOTA STATE UNIV,DEPT CHEM,CTR MAIN GRP CHEM,FARGO,ND 58105

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 22期

关键词：

D O I：

10.1021/jp960432p

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of NH2(X B-2(1)) with NO2 was studied at room temperature using time-resolved infrared diode laser spectroscopy to detect N2O, H2O, and NO products, The N2O + H2O product channel was found to have a branching ratio of 0.14 +/- 0.02. Large amounts of NO were detected, bur secondary sources of this species prevent a quantitative determination of the branching ratio into the H2NO + NO channel. These results are in contrast to previously published branching ratio data.

引用

页码：9407 / 9411

页数：5

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