A novel one-dimensional nickel(II) complex with a hydrogen-bond-link

被引：8
|
作者：
Choi, KY [1 ]
Suh, IH
Hong, CP
机构：
[1] Mokwon Univ, Dept Chem, Taejon 302729, South Korea
[2] Chungnam Natl Univ, Dept Phys, Taejon 305764, South Korea
[3] Kongju Natl Univ, Dept Chem Educ, Kongju 314701, South Korea
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 12期
基金：
新加坡国家研究基金会;
关键词：
crystal structures; nickel(II) complexes; tungstate ligand; antiferromagnetic coupling;
D O I：
10.1016/S1387-7003(99)00164-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel compound [Ni(L)(H2O)(2)](0.5)[Ni(L)(WO4)(2)](0.5). 4H(2)O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0(1.18),0(7.12)]-docosane) has been structurally and magnetically characterized. The nickel(II) ions are shown to be in distorted octahedral environments with secondary amines of macrocycles in which two trans water molecules and two trans tungstate ions are assembled around each metal center. Two nickel(II) complexes are connected into a one-dimensional chain via hydrogen bonds. The magnetic susceptibility measurement for 1 indicates weak antiferromagnetic interaction (J = -1.01(2) cm(-1); H = -J Sigma S-i. Si+1) between the S = 1 nickel(II) paramagnetic centers. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：604 / 606
页数：3
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