Is Cyanide Really a Strong-Field Ligand?

被引：16
|
作者：
Nakamura, Mikio [1 ,2 ,3 ]
机构：
[1] Toho Univ, Sch Med, Dept Chem, Ota Ku, Tokyo 1438540, Japan
[2] Toho Univ, Grad Sch Sci, Div Chem, Funabashi, Chiba 2748540, Japan
[3] Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748540, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 15期
关键词：
chromium; crystal-field theory; cyanide; iron spin states; IRON(III) PORPHYRIN COMPLEXES; ELECTRONIC-STRUCTURES; SPIN-CROSSOVER; S=3/2; STRENGTHS; STATES; PENTACYANOCHROMATE(II); COORDINATION; S=1/2; S=5/2;
D O I：
10.1002/anie.200805446
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Iron man or weakling? Ligand-field strengths are conveniently expressed by the empirical spectrochemical series. Although cyanide has been deeply entrenched as a strong-field ligand, a couple of recent examples cast doubt toward the position of this ligand, namely the high-spin (S=2) states of [CrII(CN)5]3- and [FeII(tpp)(CN)] -. tpp=meso-tetraphenylporphinate. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2638 / 2640
页数：3
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