One-Pot Curtius Rearrangement Processes from Carboxylic Acids

被引：19
|
作者：
Leogane, Olivier [1 ]
Lebel, Helene [1 ]
机构：
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
SYNTHESIS-STUTTGART | 2009年 / 11期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Curtius rearrangement; acyl azides; carbamates; protected amino acids; anilines; ureas; DIPHENYL PHOSPHORAZIDATE DPPA; CONVENIENT REAGENT; ORGANIC SYNTHESIS; INDOLES; PHOSPHORUS; CARBAMATE; AMINES; MILD;
D O I：
10.1055/s-0029-1216795
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and practical synthesis of amine derivatives from carboxylic acids is described using new one-pot Curtius rearrangement processes. The preparation of carbamate-protected amines and anilines, as well as ureas was achieved in good to excellent yields on a multigram scale.
引用
收藏
页码：1935 / 1940
页数：6
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