Synthesis and Crystal Structures of Two New Supramolecular Complexes: [Cu(tmbpm)(ox)(H2O)]•4H2O and [Zn(tmbpm)2(H2O)]•(ClO4)2•5H2O

被引：0

作者：

Ma, N. ^{[1
]}

Ji, B. M. ^{[1
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 01期

基金：

中国国家自然科学基金;

关键词：

crystal structure; hydrogen bond; synthesis; water chain; METAL-ORGANIC FRAMEWORK; ONE-DIMENSIONAL WATER; CLUSTER; LIGAND; IDENTIFICATION; CHANNEL; CU(II); TRIMER; DIMER;

D O I：

10.1080/15533174.2013.768652

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new 3D supramolecular complexes, [Cu(tmbpm) (ox)(H2O)]4H(2)O (1) and [Zn(tmbpm)(2)(H2O)](ClO4)(2)5H(2)O (2) (tmbpm = 4,4,6,6-tetramethyl-2,2-bipyrimidine, ox = C2O4 (2-)), have been synthesized and structurally characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Compound 1 is monoclinic, C2/c, a = 22.429(4) angstrom, b = 7.6501(14) angstrom, c = 25.866(6) angstrom, = 114.630(2)degrees; and compound 2 is monoclinic, C2, a = 18.854(3) angstrom, b = 7.7273(14) angstrom, c = 12.200(2) angstrom, = 93.793(2)degrees. Both compounds 1 and 2 have a mononuclear structure in which the tmbpm ligand adopts bidentate chelating coordination mode. Two 3D supramolecular structures containing 1D water chains are formed via intermolecular O-H<bold>O and O</bold>-H<bold>N hydrogen bonds</bold>. Supplementary materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.

引用

页码：106 / 111

页数：6

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