Intrasite 4f-5d electronic correlations in the quadrupolar model of the γ-α phase transition in Ce -: art. no. 054103

被引：0
|
作者：
Nikolaev, AV [1 ]
Michel, KH
机构：
[1] Univ Instelling Antwerp, Dept Phys, B-2610 Antwerp, Belgium
[2] Russian Acad Sci, Inst Phys Chem, Moscow 117915, Russia
来源：
PHYSICAL REVIEW B | 2002年 / 66卷 / 05期
关键词：
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
As a possible mechanism of the gamma-alpha phase transition in pristine cerium a change of the electronic density from a disordered state with symmetry Fm (3) over barm to an ordered state Pa (3) over bar has been proposed. Here we include on-site and intersite electron correlations involving one localized 4f electron and one conduction 5d electron per atom. The model is used to calculate the crystal field of gamma-Ce and the temperature evolution of the mean field of alpha-Ce. The formalism can be applied to crystals where quadrupolar ordering involves several electrons on the same site.
引用
收藏
页数：12
相关论文
共 50 条
  • [21] Phase transition and critical behavior of the d=3 Gross-Neveu model -: art. no. 205111
    Höfling, F
    Nowak, C
    Wetterich, C
    PHYSICAL REVIEW B, 2002, 66 (20): : 1 - 5
  • [22] Interconfiguration 4f-5d transitions of the Ce3+ ion in a LiLuF4 crystal
    Apaev, RA
    Eremin, MV
    Naumov, AK
    Semashko, VV
    Abdulsabirov, RY
    Korableva, SL
    OPTICS AND SPECTROSCOPY, 1998, 84 (05) : 735 - 737
  • [23] Interconfiguration 4f-5d transitions of the Ce3+ ion in a LiLuF4 crystal
    Apaev, R.A.
    Eremin, M.V.
    Naumov, A.K.
    Semashko, V.V.
    Abdulsabirov, R.Yu.
    Korableva, S.L.
    Optics and Spectroscopy (English translation of Optika i Spektroskopiya), 1998, 84 (05): : 735 - 737
  • [24] Phase transition in a two-dimensional Heisenberg model -: art. no. 047203
    Blöte, HWJ
    Guo, WN
    Hilhorst, HJ
    PHYSICAL REVIEW LETTERS, 2002, 88 (04) : 4
  • [25] Phase transition in a spatial Lotka-Volterra model -: art. no. 061904
    Szabó, G
    Czárán, T
    PHYSICAL REVIEW E, 2001, 63 (06):
  • [26] Application of the simple model for f-d transition to assignment of 4f-5d excitation spectra of Yb3+ doped in crystals
    Wang, Da-Jun
    Wang, Jue
    Chen, Tao
    Ma, Chong-Geng
    Yin, Min
    Xia, Shang-Da
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2009, 246 (05): : 1050 - 1055
  • [27] Role of strong electronic correlations in the metal-to-insulator transition in disordered LiAlyTi2-yO4 -: art. no. 046410
    Fazileh, F
    Gooding, RJ
    Atkinson, WA
    Johnston, DC
    PHYSICAL REVIEW LETTERS, 2006, 96 (04)
  • [28] Interplay between electronic structure and surface phase transition on α-Ga(010) -: art. no. 165422
    Sondergaard, C
    Schultz, C
    Agergaard, S
    Hoffmann, SV
    Li, Z
    Hofmann, P
    Li, H
    Grütter, C
    Bilgram, JH
    PHYSICAL REVIEW B, 2003, 67 (16):
  • [29] Quantum phase transitions in the discrete φ4 model:: The crossover between two types of transition -: art. no. 172101
    Rubtsov, AN
    Janssen, T
    PHYSICAL REVIEW B, 2001, 63 (17):
  • [30] Unravel the effect of lattice distortion on the 4f-5d excitation of Ce3+ in garnet phosphors
    Tian, Yanna
    Chen, Jie
    Yi, Xuezhuan
    Jiang, Renjie
    Lin, Hui
    Chen, Lei
    Zhou, Shengming
    JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 907
12345