Samarium(II) iodide mediated reductions -: Influence of various additives

被引：182

作者：

Dahlén, A ^{[1
]}

Hilmersson, G ^{[1
]}

机构：

[1] Univ Gothenburg, Dept Chem, S-41296 Gothenburg, Sweden

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 17期

关键词：

samarium; samarium iodide; reduction; additives; co-solvent;

D O I：

10.1002/ejic.200400442

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Samarium(II) iodide is a one-electron transfer reagent that has become highly appreciated as a mild and selective reducing agent in recent years. It has been found experimentally that various additives and co-solvents largely control the reactivity of SmI2. This microreview provides an overview of the current knowledge of the reagent SmI2 as a reducing agent, in particular with additives that increase its reactivity. The use of various proton sources is covered, as well as the effect of co-solvents. Furthermore, the very powerful reagent mixture SmI2/H2O/amine is also described. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

引用

页码：3393 / 3403

页数：11

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