Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate

被引：2
|
作者：
Kim, Nam-Ho [1 ]
Hwang, In-Chul [2 ]
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea
[2] Pohang Univ Sci & Technol, Inst Basic Sci, Pohang 790784, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809017966
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [PtCl2(C6H4NO2)(2)]center dot CH3CN, contains a neutral Pt-IV complex and an acetonitrile solvent molecule. In the complex, the Pt4+ atom is six-coordinated in a distorted octahedral environment by two N atoms and two O atoms from two pyridinecarboxylate (pic) ligands and two Cl atoms. The Cl atoms are cis with respect to each other. The compound displays inter- and intramolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen bonding.
引用
收藏
页码：M667 / U656
页数：10
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