Precise synthesis of well-defined dendrimer-like star-branched polymers by iterative methodology based on living anionic polymerization

被引：56

作者：

Hirao, Akira ^{[1
]}

Sugiyama, Kenji ^{[1
]}

Tsunoda, Yuji ^{[1
]}

Matsuo, Akira ^{[1
]}

Watanabe, Takumi ^{[1
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Sci, Polymer & Organ Mat Dept, Meguro Ku, Tokyo 1528552, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2006年 / 44卷 / 23期

关键词：

D O I：

10.1002/pola.21701

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dendrimer-like star-branched polymers recently developed as a new class of hyper-branched polymers, which resemble well-known dendrimers in branched architecture, but comprise polymer chains between junctions, are reviewed in this highlight article. In particular, we focus on the precise synthesis of various dendrimer-like star-branched polymers and block copolymers by the recently developed methodology based on iterative divergent approach using living anionic polymers and 1,1-bis(3-tert-butyldimethylsilyloxy methylphenyl)ethylene. (c) 2006 Wiley Periodicals, Inc.

引用

页码：6659 / 6687

页数：29

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