Thoria based inert matrix fuel production via sol-gel process

There is an important concern that uranium reserves will not be sufficient for new nuclear facilities in the future. Thorium could offer a potential alternative fuel because it is three times more abundant than uranium. Thorium based nuclear fuels are important candidates for the future of nuclear fuels. The main interest is in considering thorium based fuels for burning plutonium in conventional reactors. Thoria based inert matrix fuels (IMF) are also candidates for burning plutonium and the transmutation of minor actinides. In this study, inert matrix fuel production was examined by external gelation process. Metal nitrate solution of each material (thorium nitrate, cerium nitrate, aluminum nitrate and magnesium nitrate) were mixed for the feed solution. The metal nitrate solution was 50% of total feed solution. After mixing the metal nitrate, solution polyvinyl alcohol (PVA, 10%) and tetrahydrofurfuryl alcohol (THFA, 40%) were added into mixed metal nitrate solution during stirring. PVA, THFA and metal nitrate solution were dropped through a nozzle into gelation medium ammonia solution. Then external gelation process was carried out. Cerium (Ce) was used to simulate Plutonium (Pu). Obtained gels from the external gelation process were aged, washed and dried. The powders were calcinated at 1273 K for 6 h. After calcination, the powders were pressed at 500 MPa with a manual press. Pellets were sintered at elevated temperatures (1473, 1573, 1673, 1773, 1873, and 1973 K) for 4 h. The densities of sintered pellets were measured by immersion method. Sintered pellets characteristics were determined by scanning electron microscopy, x-ray diffraction analysis and energy dispersive x-ray analysis and the results were discussed. (C) 2015 Elsevier Ltd. All rights reserved.