Microwave-assisted polymerization of higher alkylene oxides

被引：26
|
作者：
Malik, Muhammad Imran [1 ,3 ]
Trathnigg, Bernd [1 ,3 ]
Kappe, C. Oliver [2 ,3 ]
机构：
[1] Karl Franzens Univ Graz, CePOL MC, A-8010 Graz, Austria
[2] Karl Franzens Univ Graz, CDLMC, A-8010 Graz, Austria
[3] Karl Franzens Univ Graz, Inst Chem, A-8010 Graz, Austria
来源：
EUROPEAN POLYMER JOURNAL | 2009年 / 45卷 / 03期
关键词：
Alkylene oxides; Microwave-assisted polymerization; Anionic ring opening polymerization; Chromatography; SIZE-EXCLUSION CHROMATOGRAPHY; LIQUID-CHROMATOGRAPHY; BLOCK-COPOLYMERS; PROPYLENE-OXIDE; CHEMICAL-COMPOSITION; POLYETHYLENE OXIDE; DIBLOCK COPOLYMERS; AQUEOUS-SOLUTIONS; COUPLED DENSITY; ETHYLENE-OXIDE;
D O I：
10.1016/j.eurpolymj.2008.11.035
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Homopolymers and block copolymers of higher epoxides (butene oxide and hexene oxide) are synthesized using 1-alkanols and PEG-MME 1100 as initiators by anionic ring opening polymerization in bulk employing controlled microwave heating in sealed vessels. The selectivity of polymerization of higher epoxides and the effect of different reaction parameters on the formation of side products is discussed. A procedure for the generation of fairly clean homopolymers and multiblock copolymers (giving bottle-brush and cone type of structures) is developed. (C) 2009 Published by Elsevier Ltd.
引用
收藏
页码：899 / 910
页数：12
相关论文
共 50 条
  • [21] Microwave-assisted aqueous RAFT polymerization of cationic monomers
    Schellinger, Joan
    Tran, Jonathan
    Ennis, Amanda
    Sherwin, William
    Luu, TinTin
    Masgsumbol, Alisson Mae
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [22] Microwave-Assisted Graft Polymerization of ε-Caprolactone onto Magnetite
    Nan, Alexandrina
    Turcu, Rodica
    Craciunescu, Izabell
    Pana, Ovidiu
    Scharf, Holger
    Liebscher, Juergen
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (20) : 5397 - 5404
  • [23] Microwave-assisted ring-opening polymerization of ε-caprolactone
    Liao, LQ
    Liu, LJ
    Zhang, C
    He, F
    Zhuo, RX
    Wan, K
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (11) : 1749 - 1755
  • [24] Microwave-assisted direct synthesis and polymerization of chiral acrylamide
    Iannelli, M
    Ritter, H
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2005, 206 (03) : 349 - 353
  • [25] Microwave-assisted atmospheric pressure plasma polymerization of hexamethyldisiloxane
    Matsubayashi, Toshiki
    Hidaka, Hiroki
    Muguruma, Hitoshi
    Japanese Journal of Applied Physics, 2016, 55 (07):
  • [26] Microwave-assisted living radical polymerization of acrylamide copolymer
    Ding, Wei
    Wang, Ling
    Yu, Tao
    Qu, Guangmiao
    Sui, Yi
    Pu, Ting
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2013, 29 (04): : 17 - 20
  • [27] Ionic liquid as surfactant in microwave-assisted emulsion polymerization
    Departamento de Engenharia Química e de Alimentos, Universidade Federal de Santa Catarina, Florianõpolis SC 88040-900, Brazil
    不详
    不详
    Sayer, C. (csayer@enq.ufsc.br), 1600, John Wiley and Sons Inc (127):
  • [28] Monomode microwave-assisted atom transfer radical polymerization
    Zhang, HQ
    Schubert, US
    MACROMOLECULAR RAPID COMMUNICATIONS, 2004, 25 (13) : 1225 - 1230
  • [29] SOME NEW CATALYSTS FOR THE POLYMERIZATION OF ALKYLENE OXIDES
    FURUKAWA, J
    TSURUTA, T
    SAEGUSA, T
    KAKOGAWA, G
    JOURNAL OF POLYMER SCIENCE, 1959, 36 (130): : 541 - 543
  • [30] Microwave-assisted synthesis of basic mixed oxides from hydrotalcites
    Cosano, D.
    Hidalgo-Carrillo, J.
    Esquivel, D.
    Romero-Salguero, F. J.
    Jimenez-Sanchidrian, C.
    Ruiz, J. R.
    JOURNAL OF POROUS MATERIALS, 2020, 27 (02) : 441 - 450
12345