Copper-Catalyzed Aerobic Oxidative Reaction of Sulfonyl Hydrazides with Alcohols: An Easy Access to Sulfinates

被引：46
|
作者：
Du, Bingnan [1 ]
Li, Zan [1 ]
Qian, Ping [1 ]
Han, Jianlin [1 ,2 ]
Pan, Yi [1 ,2 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, MaAnShan High Tech Res Inst, Maanshan 238200, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Aerobic; catalysis; copper; oxidative; sulfonyl hydrazides; ARYLSULFONYL HYDRAZIDES; STEREOSELECTIVE-SYNTHESIS; C-C; ALKENES; FUNCTIONALIZATION; SULFENYLATION; KETONES; SULFONYLHYDRAZIDES; EFFICIENT; IODINE;
D O I：
10.1002/asia.201501262
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Cu-catalyzed aerobic oxidative reaction between sulfonyl hydrazides and alcohols has been developed. In this reaction, sulfonyl hydrazides act as the sulfinic acid precursors to react with alcohols, resulting in sulfinic esters with up to 72% yield. This catalytic system tolerates a wide range of sulfonyl hydrazide substrates, and represents a new strategy for the transformation of readily available sulfonyl hydrazides.
引用
收藏
页码：478 / 481
页数：4
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