Field Demonstration of the Reversa™ Mineral Carbonation Process Using Coal and Natural Gas Flue Gas Streams

被引:0
|
作者
Prentice, Dale [1 ,2 ]
Mehdipour, Iman [3 ]
Falzone, Gabriel [4 ]
Raab, Stephen [3 ]
Simonetti, Dante [2 ,5 ]
Sant, Gaurav [1 ,2 ,6 ,7 ]
机构
[1] LC Univ Calif Los Angeles, Dept Civil & Environm Engn, Lab Chem Construct Mat, Los Angeles, CA 90095 USA
[2] Univ Calif Los Angeles, Inst Carbon Management ICM, Los Angeles, CA 90095 USA
[3] CarbonBuilt Inc, 570 Westwood Plaza, Los Angeles, CA 90095 USA
[4] RCAM Technol, Los Angeles, CA USA
[5] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
[6] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
[7] Univ Calif Los Angeles, Calif Nanosyst Inst CNSI, Los Angeles, CA 90095 USA
关键词
CO2; mineralization; Cement; utilization; CEMENTATION; COMPOSITES; LIQUID;
D O I
10.1007/978-3-030-92563-5_62
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Concrete, a mixture composed of a cementation agent, mineral aggregates, and water has the potential to serve as a gigaton-scale sink for carbon dioxide (CO2). This could make concrete the world's largest CO2 utilization opportunity. CarbonBuilt's Reversa (TM) process, developed at UCLA's Institute for Carbon Management exploits simple acid-base chemistry to mineralize CO2 -dilute flue gas emissions into mineral carbonate-based cementation agents at ambient pressure, at flue gas temperatures, and without a need for carbon capture. The approach leverages innovations in the use of portlandite (Ca(OH)(2) : calcium hydroxide, or slaked lime) which carbonates readily, and produces limestone (CaCO3 : calcium carbonate)-a potent cementation agent-upon its carbonation. Within the scope of a project sponsored by the US Department of Energy's Office of Fossil Energy, the Reversa technology was upscaled and demonstrated using a modularized pilot-plant at the Integrated Test Center (Gillette, WY) and National Carbon Capture Center (Wilsonville, AL) using coal- (similar to 12 vol. % CO2) and natural gas (similar to 4 vol. % CO2) flue gas streams. The field demonstration led to the production of over 15,000 concrete masonry units (CMUs, also known as concrete blocks) and achieved: (1) a CO2 utilization efficiency in excess of 75%, and (2) greater than 250 kg of CO2 utilization per 13 tonnes of concrete (i.e., one production run). Importantly, based on rigorous third-party validation, the CMUs produced were confirmed to be compliant with all relevant industry specifications (ASTM C90). The success of this demonstration suggests that the pioneering Reversa technology is ready for commercialization.
引用
收藏
页码:589 / 594
页数:6
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