Solvent-induced stabilization of the naphthalene anion by water molecules: A negative cluster ion photoelectron spectroscopic study

被引：61
|
作者：
Lyapustina, SA [1 ]
Xu, SK [1 ]
Nilles, JM [1 ]
Bowen, KH [1 ]
机构：
[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 2000年 / 112卷 / 15期
关键词：
D O I：
10.1063/1.481237
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We show that (a) only a single water molecule is needed to stabilize the naphthalene anion, (b) the EA(a) of naphthalene is -0.20 eV, in agreement with determinations by electron transmission spectroscopy, (c) the energetics are consistent with the number of waters required to stabilize the naphthalene anion, and (d) the excess electron is located on the naphthalene moiety of Nph(1)(-)(H2O)(n). (C) 2000 American Institute of Physics. [S0021-9606(00)00915-6].
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页码：6643 / 6648
页数：6
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