N-heterocyclic carbene-palladium complex on polystyrene resin surface as polymer-supported catalyst and its application in Suzuki cross-coupling reaction

被引：80
|
作者：
Kim, JH [1 ]
Jun, BH [1 ]
Byun, JW [1 ]
Lee, YS [1 ]
机构：
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151744, South Korea
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 30期
关键词：
polymer-supported N-heterocyclic carbene (NHC); heterogeneous catalysis; palladium (Pd); Suzuki cross-coupling; imidazolium; suspension polymerization;
D O I：
10.1016/j.tetlet.2004.06.006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A poly(imidazoliummethyl styrene)-surface grafted-polystyrene resin was prepared by suspension polymerization. This was used as the polymer-supported carbene precursor for the palladium complex, which efficiently catalyzed the Suzuki cross-coupling of aryl halides and phenylboronic acid. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5827 / 5831
页数：5
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