The synthesis of alpha-monofluorovinylphosphonates by a Peterson type olefination reaction

被引：15
|
作者：
Keeney, A [1 ]
Nieschalk, J [1 ]
OHagan, D [1 ]
机构：
[1] DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 80卷 / 01期
关键词：
synthesis; alpha-monofluorovinylphosphonates; Peterson olefination; F-19-; H-1 and P-31-NMR spectroscopy;
D O I：
10.1016/S0022-1139(96)03460-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of alpha-lithium-alpha-fluoro-alpha-trimethylsilyl-methylphosphonate 2 with aldehydes 3a-fleads to alpha-fluorovinylphosphonates 4a-fby a Peterson type olefination reaction.
引用
收藏
页码：59 / 62
页数：4
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