Structure of N,N′,N"-tris(carboxymethyl)-1,3,5-benzenetricarboxamide trihydrate

被引：12

作者：

Gong, B ^{[1
]}

Zheng, C

Yan, YF

机构：

[1] Univ Toledo, Dept Chem, Toledo, OH 43606 USA

[2] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1999年 / 29卷 / 06期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

triacid molecules; hydrogen bond interaction; water molecules;

D O I：

10.1023/A:1009511501537

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C15H15N3O9. 3H(2)O, crystallizes in the centrosymmetric space group R (3) over bar with a = 13.642(5), b = 13.642(5), c = 18.692(5) Angstrom, D-calc, = 1.440 g cm(3), and z = 6. An extensive three-dimensional hydrogen bonded network is observed. The network arises from 15 hydrogen bonds per asymmetric unit. Six identical N-H ... O hydrogen bonds are formed between two triacid molecules, which results in the face-to-face dimerization of the two triacid molecules. The dimers form extended sheets through hydrogen bond interaction with water molecules. The sheets are held together by hydrogen bonds via the water molecules. The planes of the benzenoid ring are parallel to each other.

引用

页码：649 / 652

页数：4

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