A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine

被引：57
|
作者：
Schmid, L [1 ]
Rohr, M [1 ]
Baiker, A [1 ]
机构：
[1] ETH Zentrum, Swiss Fed Inst Technol, Tech Chem Lab, CH-8092 Zurich, Switzerland
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 22期
关键词：
D O I：
10.1039/a906956i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mesoporous ruthenium silica hybrid aerogel containing well dispersed bidentate RuCl2[Ph2P(CH2)(3)PPh2](2) complexes, synthesized using a sol-gel method, affords turnover frequencies up to 18400 h(-1) and 100% selectivity from CO2, H-2 and diethylamine for the formation of N,N-diethylformamide.
引用
收藏
页码：2303 / 2304
页数：2
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