Experimental characterization of two-photon materials for fast rewritable optical data storage

被引:2
|
作者
Makarov, Nikolay [1 ]
Drobizhev, Mikhail [1 ]
Rebane, Aleks [1 ]
Peone, Desiree [1 ]
Wolleb, Heinz [2 ]
Spahni, Heinz [2 ]
机构
[1] Montana State Univ, Dept Phys, Bozeman, MT 59717 USA
[2] Ciba Specialty Chem Inc, CH-4002 Basel, Switzerland
关键词
two-photon absorption; resonance enhancement; 3D optical disk; phthalocyanines;
D O I
10.1117/12.681253
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We study one photon absorption (IPA) and two photon absorption (2PA) properties of a series of asymmetrical phthalocyanines for 2PA-based 3D optical information storage. These compounds show very large 2PA cross section, 10(3) - 10(4) GM, in near IR range of excitation, from 800 to 900 nm. This strong resonance enhancement effect is possible due to one-photon-allowed and narrow intermediate Q-transition, occurring in very vicinity of excitation wavelength. We report 2PA spectra, 2PA cross-sections, temperature stability, tautomerization and fluorescence quantum yields, measured in organic solvents and in polymer films in temperature range 77 - 300K. We show that the unique combination of photophysical properties make these compounds attractive candidates for fast re-writable volumetric storage.
引用
收藏
页数:12
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