Some successes and failures of the methods based on several experiments

被引：61
|
作者：
Ortega, A
机构：
[1] Instituto de Ciencias de Materiales, Dpto. de Quim. Inorgánica, Universidad de Sevilla, 41080 Sevilla
来源：
THERMOCHIMICA ACTA | 1996年 / 284卷 / 02期
关键词：
kinetics; solid state reaction; TG;
D O I：
10.1016/0040-6031(95)02766-1
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The actual kinetics of a solid state reaction cannot be discerned by means of the kinetic analysis of a single TG curve. The cause of this relates to the fact that different kinetic equations appear to fit a set of kinetic data. This paper shows the advantage of a choice of method based on comparing data from several experiments at the same degree of conversion. But this procedure must be carried out with great care. The limitations are discussed.
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页码：379 / 387
页数：9
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