Some successes and failures of the methods based on several experiments

被引：61
|
作者：
Ortega, A
机构：
[1] Instituto de Ciencias de Materiales, Dpto. de Quim. Inorgánica, Universidad de Sevilla, 41080 Sevilla
来源：
THERMOCHIMICA ACTA | 1996年 / 284卷 / 02期
关键词：
kinetics; solid state reaction; TG;
D O I：
10.1016/0040-6031(95)02766-1
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The actual kinetics of a solid state reaction cannot be discerned by means of the kinetic analysis of a single TG curve. The cause of this relates to the fact that different kinetic equations appear to fit a set of kinetic data. This paper shows the advantage of a choice of method based on comparing data from several experiments at the same degree of conversion. But this procedure must be carried out with great care. The limitations are discussed.
引用
收藏
页码：379 / 387
页数：9
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