Optical, infrared and EPR spectroscopy of CaF2:Ce3+ crystals co-doped with Li+ or Na+

被引:16
|
作者
Yamaga, M [1 ]
Yabashi, S
Masui, Y
Honda, M
Takahashi, H
Sakai, M
Sarukura, N
Wells, JPR
Jones, GD
机构
[1] Gifu Univ, Dept Math & Design Engn, Gifu 5011193, Japan
[2] Naruto Univ Educ, Fac Sci, Naruto 7728502, Japan
[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[4] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England
[5] Univ Canterbury, Dept Phys & Astron, Christchurch 8020, New Zealand
关键词
VUV spectroscopy; Ce3+; fluorite crystals; crystal-field analyses;
D O I
10.1016/j.jlumin.2004.01.065
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Interconfigurational 4f <----> 5d VUV absorption and luminescence, intra-4f(1) IR absorption and X-band EPR measurements have been carried out on CaF2:Ce3+ crystals co-doped with Na+ and Li+ ions. For both Li+ and Na+ co-doping, cubic, new tetragonal and rhombic-symmetry centres are observed. Cubic centres, which are readily observable by their infrared transitions, could not be identified and remain elusive in the EPR spectra. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:307 / 311
页数:5
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