Efficient Cyclometalated Platinum(II) Complex with Superior Operational Stability

被引：67
|
作者：
Zhu, Zhi-Qiang [1 ]
Klimes, Kody [1 ]
Holloway, Sean [1 ]
Li, Jian [1 ]
机构：
[1] Arizona State Univ, Mat Sci & Engn, Tempe, AZ 85287 USA
来源：
ADVANCED MATERIALS | 2017年 / 29卷 / 06期
基金：
美国国家科学基金会;
关键词：
LIGHT-EMITTING-DIODES; EXTERNAL QUANTUM EFFICIENCY; ACTIVATED DELAYED FLUORESCENCE; HIGHLY EFFICIENT; ELECTROPHOSPHORESCENT DEVICES; LONG LIFETIME; BLUE; TETRADENTATE; GREEN; EMISSION;
D O I：
10.1002/adma.201605002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A tetradentate cyclometalated Pt(II) complex (PtN3N) is developed as an efficient, stable phosphorescent emitter. One PtN3N device exhibits an estimated LT97 of 2057 h at an initial luminance of 1000 cd m(-2), while maintaining an external quantum efficiency of 15.3% at such high brightness, demonstrating performance to overcome the last technical barrier to the commercialization of Pt complexes for many applications.
引用
收藏
页数：5
相关论文
共 50 条
  • [21] Highly Efficient Blue-Emitting Cyclometalated Platinum(II) Complexes by Judicious Molecular Design
    Hang, Xiao-Chun
    Fleetham, Tyler
    Turner, Eric
    Brooks, Jason
    Li, Jian
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (26) : 6753 - 6756
  • [22] Efficient and stable red organic light emitting devices from a tetradentate cyclometalated platinum complex
    Li, Guijie
    Ecton, Jeremy
    OBrien, Barry
    Li, Jian
    ORGANIC ELECTRONICS, 2014, 15 (08) : 1862 - 1867
  • [23] Photoluminescence of a Platinum(II) Complex Containing Multiresonance B-N Motif in the Cyclometalated Ligand
    Luo, Sai
    Song, Xiu-Fang
    Jing, Yan-Yun
    Wan, Xintong
    Zhang, Jingling
    Li, Kai
    ORGANOMETALLICS, 2023, 42 (23) : 3323 - 3327
  • [24] Photocatalytic H2 evolution from water based on cyclometalated platinum(II) complex
    Xu, Quanqing
    Fu, Wen-fu
    Zhang, Guiju
    Bian, Zhaoyong
    Zhang, Junfeng
    Han, Xu
    Xu, Wenzhan
    CATALYSIS COMMUNICATIONS, 2008, 10 (01) : 49 - 52
  • [25] Cyclometalated platinum(II) complex with C∧N∧N tridentate ligand as sensitizer for lanthanide luminescence
    Chen, Kun-Jiao
    Xu, Hai-Bing
    Zhang, Li-Yi
    Chen, Zhong-Ning
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (08) : 744 - 746
  • [26] Circularly Polarized Luminescence of Cyclometalated Platinum(II) Complex Excimers: Large Difference between Isomers
    Morikubo, Jun
    Tsubomura, Taro
    INORGANIC CHEMISTRY, 2022, 61 (43) : 17154 - 17165
  • [27] Red photo- and electroluminescent half-lantern cyclometalated dinuclear platinum(II) complex
    Kinzhalov, Mikhail A.
    Katkova, Svetlana A.
    Doronina, Elizaveta P.
    Novikov, Alexander S.
    Eliseev, Ivan I.
    Ilichev, Vasiliy A.
    Kukinov, Andrey A.
    Starova, Galina L.
    Bokach, Nadezhda A.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2018, 233 (11): : 795 - 802
  • [28] Advances on supramolecular assembly of cyclometalated platinum(II) complexes
    Fu, Teng-Fei
    Ao, Lei
    Gao, Zong-Chun
    Zhang, Xiao-Long
    Wang, Feng
    CHINESE CHEMICAL LETTERS, 2016, 27 (08) : 1147 - 1154
  • [29] Cyclometalated Complexes of Platinum( II) with 2-Vinylpyridine
    Zucca, Antonio
    Maidich, Luca
    Carta, Veronica
    Petretto, Giacomo L.
    Stoccoro, Sergio
    Cinellu, Maria Agostina
    Pilo, Maria I.
    Clarkson, Guy J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014 (13) : 2278 - 2287
  • [30] C∧C* cyclometalated platinum(II) NHC complexes
    Strassner, Thomas
    Tronnier, Alexander
    Tenne, Mario
    Soellner, Johannes
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
12345