Effect of cobalt substitution on magnetic properties of Ba4Ni2-xCoxFe36O60 hexaferrite

被引:14
|
作者
Jiang, Xiaona [1 ]
Li, Songze [1 ]
Yu, Zhong [1 ]
Harris, Vincent G. [2 ]
Su, Zhijuan [2 ]
Sun, Ke [1 ]
Wu, Chuanjian [1 ]
Guo, Rongdi [1 ]
Lan, Zhongwen [1 ]
机构
[1] Univ Elect Sci & Technol China, State Key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Sichuan, Peoples R China
[2] Northeastern Univ, Dept Elect & Comp Engn, Boston, MA 02115 USA
关键词
CO;
D O I
10.1063/1.5007750
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Co-substituted U-type hexagonal ferrite bulks, with composition of Ba4Ni2-xCoxFe36 O-60 (x= 0.2, 0.4, 0.6, 0.8), were prepared by a conventional ceramic method. Saturation magnetization (4 pi Ms), coercivity (H-c), and Curie temperature (T-c) were investigated. Anisotropy constant (K-1) was calculated by fitting the magnetization curve (M-H) according to the law of approach to saturation, and anisotropy field (H-a) was calculated accordingly. The results reveal that all the samples possess the U-type hexagonal crystallographic structure. With increasing cobalt substitution content (x), the lattice parameters (a and c) almost remain the same owing to the similar radii of Ni2+ (0.72 angstrom) Co2+ (0.74 angstrom) ions. 4 pi Ms goes up, while H-c H-c shows an opposite trend. K-1 and H-a monotonously decrease resulting from that cobalt substitution weakens the c-axis orientation. Additionally, Tc increases from 467 degrees C to 484 degrees C. (C) 2018 Author(s).
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页数:5
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