The effect of elemental substitution on the electronic properties of Ru2Ge3

被引:9
|
作者
Hayward, MA [1 ]
Cava, RJ [1 ]
机构
[1] Princeton Univ, Princeton Mat Inst, Dept Chem, Princeton, NJ 08544 USA
关键词
Metalloid substitution - Ruthenium germanide;
D O I
10.1088/0953-8984/14/25/321
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The. effect of chemical substitution on the electrical resistivity and Seebeck coefficients of Ru2Ge3 is reported, with a particular emphasis on enhancing the properties relevant to thermoelectric behaviour. The properties of Ru2Ge3 itself are shown to be strongly dependent on quenching temperature. The effects of metal doping for Ru and metalloid substitution (Sn and Si) for Ge are reported. It is shown that doping of both ruthenium and germanium sites is required to reduce the high resistivity of Ru2Ge3 (similar to280 mOmega cm at 300 K) to a value of 1.5 mOmega cm, for Ru1.85Mn0.15Ge2.4Sn0.6 while maintaining high Seebeck coefficients. This latter composition has the highest thermoelectric figure of merit observed in this system: ZT(300) (K) = I X 10(-2). Unfortunately this value is too small to be competitive with existing materials.
引用
收藏
页码:6543 / 6552
页数:10
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