Mixing properties of the system methyl acetate plus methanol plus ethanol at 298.15 K

被引:32
|
作者
Rodriguez, A [1 ]
Canosa, J [1 ]
Orge, B [1 ]
Iglesias, M [1 ]
Tojo, J [1 ]
机构
[1] UNIV VIGO, DEPT INGN QUIM, VIGO 36200, SPAIN
来源
关键词
D O I
10.1021/je960158s
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper reports measurements of the densities and refractive indices of the ternary system methyl acetate+methanol+ethanol and the corresponding binary systems methyl acetate+methanol, methyl acetate+ethanol, and methanol+ethanol at 298.15 K and atmospheric pressure. A vibrating tube digital densimeter and a refractometer of synthetic sapphire prism (sodium D wavelengh) were used, the whole mole fraction range being covered. Excess molar volumes and deviations of the refractive indices on mixing were determined. Polynomials have been fitted to the results, the computed parameters being shown.
引用
收藏
页码:1446 / 1449
页数:4
相关论文
共 50 条
  • [31] Excess molar volumes of methanol or ethanol plus n-polyethers at 298.15 K
    Carmona, FJ
    Arroyo, FJ
    de la Fuente, IG
    González, JA
    Cobos, JC
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1999, 77 (10): : 1608 - 1616
  • [32] Experimental and Modeling Study on Mixing Properties of Ternary System Methyl tert-Butyl Ether plus n-Hexane plus Cyclohexane at 298.15 K
    Aliaj, Fisnik
    Hernandez, Ariel
    Zeqiraj, Arber
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2024, 45 (09)
  • [33] Mixing properties of isopropyl acetate plus aromatic hydrocarbons at 298.15 K: Density, refractive index and isentropic compressibility
    Resa, JM
    Gonzalez, C
    Diez, E
    Concha, RG
    Iglesias, M
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2004, 21 (05) : 1015 - 1025
  • [34] Salt effect on enthalpy of mixing of methanol plus ethyl acetate at 303.15 K
    Kumar, MD
    Rajendran, M
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (01): : 11 - 14
  • [35] Excess molar enthalpies for ternary mixtures of (methanol or ethanol plus water plus tributyl phosphate) at T=298.15 K
    Liu, Hong-Li
    Liu, Shi-Jun
    Chen, Qi-Yuan
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 107 (02) : 837 - 841
  • [36] Excess molar enthalpies for (acetonitrile plus 1,1-dimethylethyl methyl ether) and (methanol, or ethanol plus acetonitrile plus 1,1-dimethylethyl methyl ether) at the temperature 298.15 K
    Nagata, I
    Tamura, K
    Nishikawa, F
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (02): : 181 - 189
  • [37] EXCESS-ENTHALPIES FOR (ETHANOL PLUS PROPANONE) AND (ETHANOL PLUS PROPANONE PLUS BENZENE) AT THE TEMPERATURE 298.15 K
    NAGATA, I
    KSIAZCZAK, A
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (02): : 165 - 169
  • [38] Salting effect on the liquid-liquid equilibrium for the ternary system water plus methanol plus methyl acetate at 283.15 K
    Chen, Xiaomei
    Gao, Xu
    Zheng, Huidong
    Zhao, Suying
    Wang, Liang'en
    FLUID PHASE EQUILIBRIA, 2012, 313 : 102 - 106
  • [39] Molar volumes, molar refractions, and isentropic compressibilities of (ethanol plus methanol plus 2-methoxy-2-methylpropane) and (ethanol plus methanol plus 2-methoxy-2-methylbutane) at 298.15 K
    Arce, A
    Rodil, E
    Soto, A
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1997, 42 (04): : 721 - 726
  • [40] EXCESS-ENTHALPIES FOR (METHANOL PLUS BENZENE PLUS CYCLOHEXANE) AND (METHANOL PLUS BENZENE PLUS HEPTANE) AT THE TEMPERATURE 298.15-K
    NAGATA, I
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (12): : 1293 - 1296