Post-modified anionic nano-porous metal-organic framework as a novel catalyst for solvent-free Michael addition reactions

被引：8

作者：

Beheshti, Saeideh ^{[1
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Dept Chem, Fac Sci, Tehran, Iran

来源：

RSC ADVANCES | 2014年 / 4卷 / 70期

关键词：

FRIEDEL-CRAFTS ALKYLATION; CONJUGATE ADDITION; INDOLES; NITROALKENES; FUNCTIONALIZATION; PYRROLE; LIGAND;

D O I：

10.1039/c4ra05226a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the strategy developed here, a novel application of anionic metal-organic frameworks as heterogeneous catalysts has been introduced. We have been able to prepare a cation exchanged anionic MOF as a new heterogeneous catalytic system for solvent-free Michael addition of pyrrole to electron-deficient beta-nitrostyrenes. This catalyst was easily recovered and reused for at least six reaction cycles without a significant degradation in activity.

引用

页码：37036 / 37040

页数：5

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