Nonmetal Catalyzed Hydrogenation of Carbonyl Compounds

被引：205

作者：

Scott, Daniel J. ^{[1
]}

Fuchter, Matthew J. ^{[1
]}

Ashley, Andrew E. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 45期

基金：

英国工程与自然科学研究理事会;

关键词：

HOMOGENEOUS HYDROGENATION; METAL; HYDROSILATION; ACTIVATION; MECHANISM; ACIDITY; ETHERS;

D O I：

10.1021/ja5088979

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solutions of the Lewis acid B(C6F5)(3) in 1,4-dioxane are found to effectively catalyze the hydrogenation of a variety of ketones and aldehydes. These reactions, the first to allow entirely metal-free catalytic hydrogenation of carbonyl groups under relatively mild reaction conditions, are found to proceed via a frustrated Lewis pair mechanism in which the solvent, a weak Bronsted base yet moderately strong donor, plays a pivotal role.

引用

页码：15813 / 15816

页数：4

共 50 条

[21] Rhodium-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Carbonyl Compounds via Thiourea Hydrogen Bonding
Wen, Jialin
Jiang, Jun
Zhang, Xumu
ORGANIC LETTERS, 2016, 18 (18) : 4451 - 4453
[22] ASYMMETRIC HYDROGENATION OF CARBONYL-COMPOUNDS CATALYZED BY CHIRAL RHODIUM COMPLEXES AND THE MECHANISMS OF ASYMMETRIC INDUCTION
OJIMA, I
KOGURE, T
YODA, N
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 267 - &
[23] One-pot reductive amination of carbonyl compounds and nitro compounds via Ir-catalyzed transfer hydrogenation
Luo, Renshi
Tong, Jinghui
Ouyang, Lu
Liu, Liang
Liao, Jianhua
RSC ADVANCES, 2023, 13 (42) : 29607 - 29612
[24] Advances in Transfer Hydrogenation of Carbonyl Compounds in Water
He, Yan-Mei
Fan, Qing-Hua
CHEMCATCHEM, 2015, 7 (03) : 398 - 400
[25] Selective Transfer Hydrogenation of α,β-Unsaturated Carbonyl Compounds
Farrar-Tobar, Ronald A.
Tin, Sergey
de Vries, Johannes G.
ORGANOMETALLICS FOR GREEN CATALYSIS, 2019, 63 : 193 - 224
[26] CATALYTIC IONIC HYDROGENATION OF CARBONYL-COMPOUNDS
KALINKIN, MI
PARNES, ZN
SHAAPUNI, DK
KURSANOV, DN
DOKLADY AKADEMII NAUK SSSR, 1976, 230 (01): : 99 - 101
[27] CHEMOSELECTIVE HYDROGENATION OF UNSATURATED CARBONYL-COMPOUNDS
GALLEZOT, P
RICHARD, D
ERDOL & KOHLE ERDGAS PETROCHEMIE, 1994, 47 (7-8): : 283 - 286
[28] Simple manganese carbonyl catalyzed hydrogenation of quinolines and imines
Wang, Zelong
Chen, Lei
Mao, Guoliang
Wang, Congyang
CHINESE CHEMICAL LETTERS, 2020, 31 (07) : 1890 - 1894
[29] Simple manganese carbonyl catalyzed hydrogenation of quinolines and imines
Zelong Wang
Lei Chen
Guoliang Mao
Congyang Wang
ChineseChemicalLetters, 2020, 31 (07) : 1890 - 1894
[30] Transfer hydrogenation of carbonyl compounds and alkenes catalyzed by ruthenium(II)-N-heterocycle carbene complexes
Fekete, Marianna
Joo, Ferenc
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2007, 72 (08) : 1037 - 1045

← 1 2 3 4 5 →