Development of ansa-Metallocene Catalysts for Isotactic Olefin Polymerization

被引：34

作者：

Brintzinger, Hans H. ^{[1
]}

Fischer, David ^{[2
]}

机构：

[1] Univ Konstanz, D-78457 Constance, Germany

[2] Albemarle Corp, Baton Rouge, LA 70801 USA

来源：

POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS | 2013年 / 258卷

关键词：

Activation; ansa-Zirconocene catalysts; Constrained-geometry catalysts; ethene/propene rubbers; Isotactic polypropylene; Linear low-density polyethylene; Molar-mass distribution; Olefin polymerization; Reaction mechanisms; Single-site catalysts; Stereosectivity; BRIDGED TETRAHYDROINDENYL LIGANDS; PROPENE POLYMERIZATION; PROPYLENE POLYMERIZATIONS; ZIRCONOCENE CATALYSTS; METHYLALUMINOXANE CATALYST; CRYSTAL-STRUCTURE; CHAIN TRANSFER; DERIVATIVES; ACTIVATION; COMPLEXES;

D O I：

10.1007/12_2013_215

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The development of ansa-metallocene catalysts is considered along several lines of interest - ansa-metallocene complexes with different ligand frameworks, insights gained with regard to relevant reaction intermediates and contributions of ansa-metallocene catalysts to industrial polymer production - with a view toward the present state of the art in these fields of catalysis research.

引用

页码：29 / 42

页数：14

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